Chemistry of UV Detecting Beads

November 13, 2009

ronby: Ron Perkins

UV-sensitive beads contain pigments that change color when exposed to ultraviolet light from the sun or certain other UV sources. The electromagnetic radiation needed to affect change is between 360 and 300 nm in wavelength. This includes the high-energy part of UV Type A (400-320 nm) and the low energy part of UV Type B (320-280 nm). Long wave fluorescent type black lights work well; incandescent black lights and UV-C lamps will not change the color of the beads.

The dye molecules consist of two large, planar, conjugated systems that are orthogonal to one another. No resonance occurs between two orthogonal parts of a molecule. Imagine two planes at right angles to one another, connected by a carbon atom. When high energyuv651 UV light excites the central carbon atom, the two smaller planar conjugated parts form one large conjugated planar molecule. Initially neither of the two planar conjugated parts of the molecule is large enough to absorb visible light and the dye remains colorless. When excited with UV radiation, the resulting larger planar conjugated molecule absorbs certain wavelengths of visible light resulting in a color. The longer is the conjugated chain; the longer the wavelength of light absorbed by the molecule. By changing the size of the two conjugated sections of the molecule, different dye colors can be produced. Heat from the surroundings provides the activation energy needed to return the planar form of the molecule back to its lower energy orthogonal colorless structure.

Although UV light is needed to excite the molecule to form the high-energy planar structure, heat from the surroundings provides the activation energy to change the molecule back to its colorless structure. If colored beads are placed in liquid nitrogen, they will not have enough activation energy to return to the colorless form.

The UV detecting beads remain one of the least expensive qualitative UV detectors available today. They cycle back and forth thousands of times.


Ultraviolet Scavenger Hunt

June 25, 2009

LaurieNBy: Laurie Neilsen

When many people think of UV lights or black lights, they think of posters in college dorm rooms, or spooky Halloween displays. Ultraviolet light, however, is an important subject of scientific study. Occupying the segment of the electromagnetic wavelength spectrum between 10 nm and 400 nm, Ultraviolet light is invisible to the human eye. UV lights are often referred to as “black” lights because of this.

The Ultraviolet Flashlights available from Educational Innovations emit long-wave UV light at 385 nm. When the invisible ultraviolet light shines on a fluorescent substance, the light emitted is slightly less energetic. The loss of energy lengthens the wavelength of the light, bringing it above 400 nm, and into the visible spectrum. Materials which have this reaction to UV light are all around us in our daily lives.

I went home one day with one of our 51-bulb Long-Wave UV Flashlights to make note of what in my apartment does and does not fluoresce. Some were items I expected, like whiteuv651 paper. Many of my books and many of the labels on products throughout my home glowed brightly under the UV light. Likewise, many white fabrics also fluoresced, including dryer sheets and some old insulation around our doorways. The text on one of my posters seemed to nearly jump off the paper, even though it is not a poster designed to make college students say “whoa.”

I was not surprised to find that many items commonly called “neon” glow under a blacklight. There were several Lego pieces which glowed quite brightly, usually the headlights on the vehicles. Any brightly colored labels or plastic packaging lit up, as did some clear plastic packages. I was surprised to see that some of the glasses in my cupboard seemed to glow faintly, usually those with thick bottoms.

A trip into my pantry revealed a few surprises. Both shortening and canola oil reacted to the light, as did tonic water. The bright packaging of my cheese snacks reacted, but the cheese snacks themselves did not glow as brightly as I thought they might. I knew that liquid detergent is reactive to UV light, but I use powder detergent. Although it did not all glow, there were several brightly glowing particles within the detergent. I wonder if this is what is used to make white clothes look whiter.

bug720sI looked into my jewelry box to see that a few of the beads were glowing. I have a necklace from the people who bring us our Real Cool Bugs. Mine has a green chafer beetle in it, whose eyes apparently react to UV light. It looked as if I had somehow turned its little headlights on.

As I wandered through the apartment, I noticed that the dust (in what I thought was a pretty clean apartment) was glowing under the UV light. I turned the flashlight on my skin, and saw that I fluoresce as well. Perhaps I should get out in sunlight a little more often.

Remembering far too many crime shows from television, I turned the light on my floor. I saw something glowing brightly on one of the rugs. With the lights on, there appeared to be nothing there. I am assuming the crime that took place there involved a ball of fur escaping the confines of my cat’s stomach. I then made the grave mistake of turning the light on my tub and sink in the bathroom. Do yourself a favor, and never look at your tub in the dark with a UV light. I’m hoping soap scum was the reason for the streaks and spots that I saw. If I ever want to sleep again, that was just soap scum.

Having explored most of my home, I turned the UV light onto the walls. I could clearly see the spots where holes in the plaster walls were filled in, and possibly painted over with new paint. The old paint on the walls had no reaction at all to the light, despite being white paint. Newer paint has brighteners that cause a reaction to UV light. Considering how old the house is, and how much the plaster walls tend to break apart in big chunks when drilled into, a UV light could be a handy tool in finding places where a hole might be easier to drill.

Science is about asking questions and finding answers. Therefore, the Scientific Process requires a healthy dose of curiosity. Send your students on their own ultraviolet scavenger hunts, and see what they find. The answers may surprise you.


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